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Elastomer Stereospecific Polymerization (Advances in Chemistry Series, Volume 052) - PDF
Elastomer Stereospecific Polymerization (Advances in Chemistry Series, Volume 052) - PDF
نویسندگان: B. L. Johnson and Murray Goodman خلاصه: Addition polymerization, initiated by organometallic compounds, has in recent years aroused widespread interest mainly because of the stereospeciflc character of many of these systems. It soon became apparent that the chain propagation reaction in these systems differed markedly from that of the wellknown free radical polymerizations in that it involved an orientation of the incoming monomer instead of a more random reaction. However, elucidating the detailed mechanism of this important step has been difficult owing to lack of knowledge about the exact structure of the organometallic compound as well as the heterogeneous nature of most such systems. The available knowledge of stereoregular polymerization (1), anionic propagation kinetics (13), and organolithium polymerization (2) has recently been reviewed. Based on presently available knowledge, therefore, it is now possible to sketch some general guide lines toward a better understanding of these phenomena.

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